With out excessive warning, we could pull high-carbon fuels into the worth chain in pursuit of the zero-emissions dream.

The world’s first hydrogen tanker masses its first cargo of coal-based H2 for the Japanese-Australian HESC mission, January 2022 (HESC)

Feb 4, 2022 4:15 PM by

Paul Blomerus

International locations world wide are adopting greenhouse fuel (GHG) emissions targets of zero emissions by 2050. The worldwide marine delivery business can be evaluating whether or not to extend the present Worldwide Maritime Group agreed goal of a 50 % discount by 2050 to a one hundred pc discount. Massive worldwide delivery corporations equivalent to Maersk, MSC and CMA CGM, have already dedicated to attain carbon neutrality by 2050 or sooner.

Changing the present fossil fuels utilized in ships – equivalent to heavy gas oil – with cleaner various fuels may present options to the problem of decarbonization and Clear Seas’ ongoing analysis on decreasing GHGs from marine fuels offers some invaluable insights.

Electrify the gas

To discover a path to zero-carbon marine delivery, the whole system from gas manufacturing by means of to its consumption to propel the ship must be thought-about. Thankfully, years of innovation have made ships essentially the most environment friendly type of transport worldwide, and allowed the event of essentially the most fuel-efficient engines and propeller drives. Power effectivity measures – equivalent to utilizing excessive tech sails – may also help cut back the quantity of gas ships want, however the remaining vitality wanted to energy ships has to come back from someplace. Might renewable electrical energy be used as a clear supply of energy?

Electrification holds nice promise for decreasing GHG emissions from a complete vary of present fossil gas intensive processes in business, house heating and automobiles. It’s because renewable low-carbon electrical energy from wind and photo voltaic has fallen in price to make it a plentiful and economically viable various.

However how can we get this cleaner electrical energy from the supply to the ships? Batteries are an incredible choice for brief journeys on vessels like ferries and pleasure boats, however for large-scale ocean transport they’re too heavy and hulking to retailer the required vitality. That is the place various fuels are available. By changing electrical energy into fuels – so referred to as e-fuels – there’s a potential means to resolve the issue of methods to transport the electrical energy to the ships.

Hydrogen as a constructing block

The easiest way scientists and engineers have discovered to transform electrical energy right into a gas is thru a course of referred to as electrolysis that splits water (H2O) into the hydrogen and oxygen it’s manufactured from by operating electrical energy by means of it in an electrolyzer. Massive quantities of electrical energy are required for this course of – all the each day common electrical energy consumed by a Canadian family would solely make half a kilogram of hydrogen by means of electrolysis, with the equal vitality content material to drive a household automobile simply 12 miles. However the result’s hydrogen fuel produced with none fossil fuels – known as “inexperienced” hydrogen.

Sadly, hydrogen alone shouldn’t be an excellent gas for ships. Although hydrogen will be burned fairly effectively within the ship’s engine, refueling and storage onboard the ship presents a major problem. Hydrogen is a extremely flammable, lighter than air fuel and, even when pressurized into cylinders or liquified by means of a cooling course of, it stays too cumbersome within the portions required to interchange common marine gas. Hydrogen storage tanks are additionally pricey, heavy and vitality intensive to fill.

Instance of a hydrogen manufacturing facility idea powered with renewable vitality sources. The hydrogen plant to be in-built Varennes, Quebec, will use hydroelectric energy.

However all shouldn’t be misplaced for various fuels. By combining the inexperienced hydrogen produced by means of electrolysis with different gases like nitrogen, carbon dioxide and oxygen, discovered within the environment, easy compounds like ammonia, methanol and methane will be manufactured and extra simply saved in ship gas tanks within the portions required. These chemical compounds can nonetheless be burned in present ship engines if small modifications are made to their design and development. However to make these artificial various fuels out of hydrogen, sustainable sources of the opposite chemical parts are wanted.

Ammonia gas is a entrance runner but it surely’s poisonous

Of the artificial various fuels into account, manufacturing ammonia from inexperienced hydrogen is probably the best. The method is extensively used as we speak for fertilizer manufacturing and the one different aspect required for ammonia, chemical components NH3, is nitrogen – and that is in plentiful provide within the air that surrounds us. The unhealthy information is that separating the nitrogen from the air is an vitality intensive course of, as is the ammonia manufacture. One other problem with ammonia is that if spilled, it might flip right into a poisonous vapour cloud that’s lethal for people and animals. So why is ammonia even thought-about? Its ease of manufacture on an enormous industrial scale and our expertise in safely transporting it in bulk on ships, trains and vans for the fertilizer business are good causes to again ammonia within the various fuels race.

The ammonia molecule (components NH3)

Burning ammonia in a ship engine has been confirmed to be attainable, and though there are considerations concerning GHG emissions from the nitrous oxides produced in its exhaust in addition to the smog-producing nitrogen oxides (NOx), these appear like they are often managed. Ammonia fuel will be became liquid for transportation and storage by chilling it to a comparatively modest -27 levels F.

Methane gas attracts on fossil gas expertise

Artificial e-methane has a bonus over ammonia in that its fossil precursor has already been extensively used as a ship gas within the type of liquefied pure fuel. Which means that we have already got processes, requirements and rules for the protected design and operation of ships utilizing methane as a gas. Nevertheless, one main downside of artificial methane is that, just like the prime part of fossil pure fuel, it’s itself a greenhouse fuel. Although comparatively quick lived in comparison with carbon dioxide, its unintended launch would must be vigilantly prevented in an identical solution to different artificial GHGs like refrigerants.

The second drawback is one which it shares with methanol: manufacturing methane (chemical components CH4) requires the addition of carbon represented by C within the components. Though carbon within the type of carbon dioxide emissions from fossil gas combustion surrounds us, capturing it and utilizing this supply of carbon doesn’t produce zero GHG gas as a result of the carbon originates from a fossil supply.

As a substitute, producers of zero GHG methane must both seize carbon dioxide (CO2) from the combustion of plant matter, for instance at pulp mills or wood-fired energy vegetation, or seize it immediately from the environment.

The availability of carbon dioxide from organic sources like wooden that captured the carbon dioxide from the environment by means of pure processes is proscribed, so long-term options for zero GHG marine fuels would want to depend on so-called direct air seize strategies that chemically extract carbon dioxide from the environment. It stays to be seen if the price of carbon captured this manner will be decreased low sufficient by means of scaling up of those processes to make artificial fuels containing direct air captured carbon dioxide.

The methane molecule (components CH4)

Methane’s primary benefit over different artificial fuels is that it may be utilized in present LNG-fuelled ships with out modification and might make the most of the present and rising infrastructure constructed for the transportation of fossil fuels. The identical infrastructure and gas tanks may doubtlessly even be used to retailer ammonia, regardless that its storage temperature of -27 F shouldn’t be practically as little as the -260 F that’s required for LNG. Ammonia has the next density than liquefied methane, so this is able to additionally must be factored in to designs of LNG gas infrastructure.

Methanol gas is a fancy however simpler to handle various

Methanol, whereas nonetheless poisonous, can be simpler to handle than each ammonia and methane as a result of it’s a liquid at room temperature. There may be vital expertise safely transporting it in bulk on ships for the worldwide chemical commerce and burning it in an engine appears to current few issues.

Methanex Corp., of Vancouver, B.C., operates the most important fleet of methanol tankers on the earth, a rising proportion of which at the moment are outfitted with methanol burning engines. Sadly, the methanol burned in these engines is produced from fossil pure fuel, and Clear Seas analysis has revealed that extra GHG emissions come from this fossil methanol than from present fossil fuels produced from oil.

However the fossil methanol manufacturing infrastructure additionally presents a possibility. Normally, industrial methanol is produced utilizing hydrogen made by splitting fossil pure fuel in a steam methane reformer. Step one in producing zero GHG methanol is to substitute the hydrogen from fossil pure fuel with inexperienced hydrogen produced from electrolysis. Sadly, like methane, methanol additionally requires a supply of carbon as a result of its chemical components (CH3OH) accommodates a C for carbon. Like e-methane, direct air seize of atmospheric carbon dioxide would as soon as once more must be deployed to fabricate e-methanol.

The methanol molecule (components CH3OH)

The problem of scaling up inexperienced hydrogen manufacturing from electrolysis

Ammonia, methane, and methanol depend on a plentiful provide of inexperienced hydrogen from electrolysis. That is the essential and doubtlessly weakest hyperlink within the chain. Plans are beginning to be implement to develop a community of inexperienced hydrogen manufacturing amenities and Canada’s low-carbon electrical energy grid equipped by means of hydroelectric energy makes it a beautiful location. Varennes, Que., would be the web site of one of many world’s largest inexperienced hydrogen amenities. Costing $200 million, the plant will devour 88 megawatts of electrical energy and produce 11,000 tonnes of hydrogen yearly. However this solely equates to sufficient vitality to provide simply over half the gas wanted for a single massive container ship with pure hydrogen.

Clearly, it’s not economically viable or sensible for every ship to have two $200 million gas manufacturing amenities supplying it. Advances in electrolysis expertise will probably be required to enhance the output, however elementary limitations created by the chemical vitality required to separate water molecules make this a problem – a most of simply 26 grams of hydrogen for each kilowatt hour of electrical energy consumed. So, if the Varennes plant could possibly be made one hundred pc environment friendly and ran 24 hours a day, its output would solely enhance to twenty,000 tonnes of hydrogen per 12 months, sufficient for one container ship. Making the artificial ammonia, methanol or methane with the hydrogen does make it go a bit additional, however making sufficient inexperienced hydrogen to decarbonize the worldwide marine delivery business stays a major problem.

Might hydrogen from fossil pure fuel bridge the hole?

Hydrogen for the petrochemical business is often produced by heating fossil pure fuel within the presence of steam – so referred to as steam methane reforming. Might this be used to substitute for the inexperienced hydrogen till electrolysis expertise is improved? Clear Seas analysis signifies that hydrogen produced by means of this technique emits extra GHGs than typical marine gas produced from oil. It shouldn’t be thought-about as a substitute.

Carbon seize and sequestration is usually proposed to repair this drawback of extreme carbon dioxide emissions created when hydrogen is produced from pure fuel. Canada is the positioning of one of many largest carbon seize and sequestration vegetation on the earth. Shell Canada’s Quest facility close to Edmonton, Alberta price $1.35 billion and might seize and retailer simply over 1 million tonnes of carbon dioxide per 12 months in underground caverns. This may increasingly sound like plenty of carbon dioxide, however in actuality, it equates to the annual carbon dioxide emissions of simply 5 massive container ships.

Though Shell plans to broaden the capability for carbon dioxide seize and sequestration to virtually 10 instances the Quest facility, these tasks are primarily designed to cope with the emissions from Shell’s fuel processing and oil refineries and will by no means deal with the emissions from large-scale hydrogen manufacturing for marine gas. And even when seize and sequestration could possibly be scaled up, there may be uncertainty within the scientific neighborhood concerning the capability of the underground rock formations to sequester carbon dioxide with out it leaking out over time.

Canadian renewable vitality firm Ekona Energy Inc., of Burnaby, B.C., is piloting another expertise referred to as pyrolysis that splits the methane in pure fuel into hydrogen and carbon mud. This carbon mud could possibly be extra simply managed and disposed of than carbon dioxide fuel, however the expertise remains to be at a really early stage of growth.

How about biofuels?

Biofuel variations of each methane and methanol will be produced from any natural materials. Crops are the place most natural materials comes from, and so they seize carbon dioxide from the environment as they develop, so when they’re became gas to be burned it’s thought-about carbon impartial.

Bio-methanol will be produced by heating wooden chips till they produce a fuel after which cleansing and purifying that fuel to create the ultimate product. Methanol can be produced in wooden pulp mills as a by-product of the pulping course of, however that is often burned by the pulp mills to generate vitality. In principle, these sources of bio-methanol could possibly be directed to offering ship gas. However international manufacturing of bio-methanol is at present extraordinarily restricted and is estimated at solely 0.2 million tonnes per 12 months by the Worldwide Renewable Power Affiliation. This could solely be sufficient gas for fewer than two massive container ships.

Bio-methane is extra frequent than bio-methanol, and the Canadian Biogas Affiliation calculates that six petajoules of fuel is at present produced at 280 websites throughout Canada alone. These embody digesters of animal waste in addition to fuel captured from landfills and sewage therapy works. For context, six petajoules is just sufficient fuel to gas two or three massive container ships.

These two examples illustrate the immense scale of the problem to supply biofuels to be used within the marine delivery business. With rising demand for net-zero emission fuels, competitors for the natural uncooked supplies for gas manufacturing will solely intensify. Devoted sources of natural matter for fuels like genetically engineered algae have did not ship, and considerations concerning the native ecological and local weather change impacts of land-use modifications from new vegetation plantations make these choices much less and fewer viable. Although biofuels may play a job within the transition to zero GHG marine fuels, it’ll possible solely be a restricted one.

Extra work is required to attain zero greenhouse fuel emissions from marine fuels

Contemplating the complete vitality system from gas manufacturing by means of to vitality use on the ship, ship expertise shouldn’t be essentially the weak hyperlink within the chain. Options for gas tanks and engines that may retailer and burn zero GHG emissions various fuels are prepared now or have growth applications properly underway. Retrofitting the massive 2-stroke engines predominately utilized in ocean-going ships to permit them to burn any mixture of other fuels seems to be comparatively simply completed, and ship designers are responding to the problem of modularization of gas storage to permit methane, ammonia or methanol tanks to be put in in present ships.

The crucial gaps appear to be upstream within the gas manufacturing a part of the worth chain, and the large-scale manufacturing of inexperienced hydrogen from electrolysis. Present options will want vital advances to scale as much as the volumes of manufacturing wanted. If methane or methanol are for use, then main advances in direct air seize of carbon dioxide may even be wanted to supply the opposite uncooked supplies for the gas. Biofuels may also help within the interim, however solely a tiny quantity and so they don’t current an answer for the full-scale decarbonization of marine delivery.

It seems that extending our reliance on fossil fuels with carbon seize and sequestration of both carbon dioxide or strong carbon could must be thought-about as a least unhealthy interim choice, however excessive warning is required to protect towards unintentionally bringing larger carbon depth fuels into the worth chain within the pursuit of the zero GHG emissions marine gas dream that will by no means be really realized.

Though synthesized various fuels present a possible pathway to zero GHG marine delivery by 2050, it’s nonetheless a slender and treacherous one, and there may be definitely scope for innovation and extra radical options to assist open the way in which to a really fossil gas free future.

Paul Blomerus is the Govt Director of Clear Seas and an internationally-experienced researcher and chief in innovation with a confirmed observe report in business and college analysis administration. He holds a Ph. D. in Engineering Science from the College of Oxford, England, and a Mechanical Engineering diploma with first-class honors from the College of Cape City, in South Africa.

This text seems courtesy of Clear Seas and could also be present in its authentic type right here.

The opinions expressed herein are the creator’s and never essentially these of The Maritime Govt.